Results of the study of the conditions of detection of traces of marking agents added to industrial plastic explosives in air using preconcentration and subsequent analysis on a ECHO-V-IDVS modernized gas chromatograph with a polycapillary column, an ionization detector of a varying selectivity (IDVS), and atmospheric air as a carrier gas are presented. A significant effect of air humidity on the limits of detection for 4-nitrotoluene and 2,3-dimethyl-2,3-dinitrobutane is demonstrated; the highest IDVS sensitivity was observed at the humidity of the carrier gas less than 8.5 mg/m³. For the preconcentration of marking agents, concentrators based on Tenax adsorbent or those produced as metal wire grids coated with a stationary phase are most efficient. The limits of detection for vapors of marking agents in sampling 1 L of air to a concentrator are 22 pg/cm³ for 4-nitrotoluene and 0.1 pg/cm³ for 2,3-dimethyl-2,3-dinitrobutane.